Sod. bicarbonate is a good buffering agent. Apart from that bentonites do have role, caco3 could also be useful. MgO again has cation exchange action which helps in acid neutralization. A combination of sod. bicarb and magnesium oxide works well in acidosis.
Normally 100-120 gr. x cow x day of sodium bicarbonate are enought. You can also work with 1% of calcium in the total diet, and add 50 gr. of MgO.
In any case a 50/50 forgage concentrate, if you are usin part of the forage like raygrass (with a great rumination efficiency) doesn't cretae problems of acidosis
First of all I am concerned that you want to enhance the level of concentrate feeding when in fact that will affect rumen condition, alter the micro-flora population and render fibre less digestible. That kind of practice goes against the principle of taking advantage of the symbiotic relationship that exists between the host animal and the rumen bacteria to produce milk and meat.
If you have access to supplements with protected fats, amino acids and soluble sugars, you can in fact feed more roughage and benefit from optimal rumen digestion. That way, you still achieve higher yields from the supplements that are more efficiently utilised in the lower gut.
Should the above not be a viable option then you may consider feeding rumen buffers, thoroughly mixing the concentrates and roughage and offering the feed continuously.